Three physical characteristics give reinforced concrete its special properties: 1.The coefficient of thermal expansion of concrete is similar to that of steel, eliminating large internal stresses due to differences in thermal expansion or contraction. 2.When the cement paste within the concrete hardens, this conforms to the surface details of the steel, permitting any stress to be transmitted efficiently between the different materials. Usually steel bars are roughened or corrugated to further improve the bond or cohesion between the concrete and steel. 3.The alkaline chemical environment provided by the alkali reserve (KOH, NaOH) and the portlandite (calcium hydroxide) contained in the hardened cement paste causes a passivating film to form on the surface of the steel, making it much more resistant to corrosion than it would be in neutral or acidic conditions. When the cement paste exposed to the air and meteoric water reacts with the atmospheric CO2, portlandite and the Calcium Silicate Hydrate (CSH) of the hardened cement paste become progressively carbonated and the high pH gradually decreases from 13.5 – 12.5 to 8.5, the pH of water in equilibrium with calcite (calcium carbonate) and the steel is no longer passivated.
Posted on: Sun, 27 Apr 2014 02:30:05 +0000